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Process · Platinum/palladium

Calibrate your platinum/palladium before committing the Pt/Pd.

At €5 per A4 sheet and 300+ usable grey levels, calibrating is no longer a comfort. Fifteen minutes of measurement, a 16-point `.acv` curve (Pro mode), and the whole tonal range finally readable.

Reviewed by Tristan Sidem + Raphaël Lebas de Lacour

Platinum/palladium practitioner coating cotton paper with Pt/Pd chemistry

Le problème

Sound familiar?

  1. 01

    Tonal range crushed to 150 levels

    Platinum/palladium can use 300+ levels. Without calibration your negative uses only half — you pay for palladium to get greys linearised at a loss.

  2. 02

    Shadows blocked in the deep blacks

    The 1.8 Dmax of Pt/Pd is never reached without a curve. Shadow detail is lost in a uniform black.

  3. 03

    Cost piling up with every test

    Three failed prints = €15 of chemistry + an €8 A4 cotton-rag sheet. Calibration pays for its own session from the second series.

Demonstration · Before / after calibration

The difference on a platinum/palladium print

The same source file, printed without calibration on the left and calibrated with Calibration Flow on the right. You can see how calibration frees the full tonal range of your platinum/palladium process.

Before/after diptych — platinum/palladium, full tonal range
↳ Left: blocked shadows, a plateau in the midtones, flat highlights↳ Right: the full tonal range, an even progression across the 25 steps

Spécificités du procédé

Expensive, wide, slow — calibratable in advance.

Platinum/palladium printing relies on the UV reduction of ferric salts, which in turn catalyses the deposition of metallic platinum or palladium in the paper fibre. The result: a print with an exceptionally wide tonal range — about 300+ distinct grey levels used — and museum-grade permanence (several attested centuries).

The chemistry cost is very high: between €4 and €8 per A4 sheet depending on the chosen Pt/Pd ratio and sensitisation dose. At that level, printing blind is not a viable option. Calibrating before each series, or at least at every substantial change of chemistry or paper, becomes an economic condition of the process.

The typical Dmax is 1.8 on Hahnemühle Platinum Rag, a paper formulated specifically for the process. On other heavy cotton papers you get a Dmax between 1.6 and 1.75. The development bath (potassium oxalate or sodium citrate) is temperature-sensitive: 20 °C produces softer highlights, 30 °C lightens them and raises contrast. Calibrate at the temperature you will print at in production.

Target polarity: negative, like all contact-exposure processes (except resinotype). The sensitiser contains a small amount of potassium dichromate as a contrast agent — the dichromate concentration changes your curve’s slope and must be stabilised before calibration.

Référence externe : Wikipedia

Interactive tool · Printable target

Generate your platinum/palladium target now

25-patch target (5×5 grid + continuous gradient), equal steps of about 4.2 % in grey value, from white to black. Negative polarity (matches this process). Download, print on inkjet transparency with colour management off, expose onto your sensitised paper.

Print the target on your negative, in the app

Downloaded file at 1680×1410 px (300 dpi), free, no sign-up. In the app, a 25-step grey grid and its gradient print straight onto a corner of your negative (Target → Show the target tab) and get the same curve as the image.

Target computed like the app’s: evenly spaced grey steps and a continuous gradient. On a scan, the app reads each step as perceptual lightness, L* (CIELAB).

Workflow en 3 étapes

Mire, insolation, courbe.

  1. Print the 25-patch negative target on transparency

    Negative polarity, no colour management, on the same paper as your final print (Hahnemühle Platinum Rag preferred).

  2. Sensitise, expose, develop at controlled temperature

    Pt/Pd + dichromate sensitisation, UV exposure, development at production temperature (20-30 °C). Read after stabilised drying.

  3. Export the .acv curve for Photoshop or Affinity Photo (Pro Mode)

    A 16-point Adobe `.acv` curve, exported in one click, ready to apply to your production negatives. .acv export is reserved for Pro mode (€9.90/month).

Demo · 3 sliders, one corrective curve

Adjust the curve live

Calibration Flow corrects any non-linear response with three sliders. No point to draw with the mouse, no Bézier handle to wrangle. Play with the values below and see the effect on the curve and on the platinum/palladium tonal rendering immediately.

Input 0–255 ↔ Output 0–255

Minimum input threshold. Everything below it becomes pure black.

Maximum input threshold. Everything above it becomes pure white.

Midtone curvature. 1.00 = linear, < 1 = darker mid-tones, > 1 = lighter mid-tones.

Source gradient (before correction)

Corrected gradient (after applying the curve)

This demo applies a simple formula (black/white points + gamma exponent) for illustration. The app additionally uses a robust LOWESS + monotone PCHIP smoothing pass that rounds off transitions without creating artefacts. The Mode Pro (€9.90/month) then lets you export a .acv file, loadable into Photoshop or Affinity Photo in two clicks.

Tristan Sidem and Raphaël Lebas de Lacour in an alt-process workshop, holding a test target

Preuve d'autorité

Pourquoi nous faire confiance.

« Platinum/palladium is the process that makes software calibration legitimate. At that chemistry cost, you no longer print on instinct. Calibration Flow does not replace the practitioner’s eye — it preserves the tests you will not redo. »

Tristan Sidem — founder of Calibration Flow + Vision Picturale

Références techniques

  • Christopher James — The Book of Alternative Processes (chapters 16-18 on platinum and palladium printing)
  • Bostick & Sullivan — reference Pt/Pd sensitisers
  • Dick Stevens — Making Kallitypes and Platinotypes
  • Mark Nelson — PDN method applied to platinum

Signé

  • Tristan Sidem — founder of Calibration Flow + Vision Picturale
  • Raphaël Lebas de Lacour — co-founder of Vision Picturale

Access & pricing

Try Calibration Flow.

  • Web

    Free with account

    • 3 curves, unlimited presets, 10 HD scans, 300 MB storage
    • No credit card required
    Try the Web version
  • Pro · Web + iOS

    €9.90/month

    • .acv export for Photoshop/Lightroom
    • HD Full Gamut export (5-7 inks) & advanced separation settings
    • 100 HD scans, 5 GB cloud storage
    • One subscription for Web + iOS, cancel anytime
    See on the App Store
  • Code Luminograph

    1 year of Pro included

    • Shipped with the purchase of a Luminograph at Vision Picturale (€449 A4 / €699 A3+)
    • One year of Pro mode, then reverts to free
    • Extended quotas and 5 GB of cloud storage
    Discover the Luminograph

Comparatif honnête

Calibration Flow face aux alternatives.

Comparatif Calibration Flow vs QuadToneRIP vs PiezoDN vs méthode manuelle
DimensionCalibration FlowQuadToneRIPPiezoDNMéthode manuelle
Tonal precision16 .acv pointsVery highMaximalManual
Learning curve~15 min~2 days~1 weekVariable
Entry price€0 (free)~$50~$300~€400
.acv outputNative (Pro mode)NoNoTo be drawn
Mobile✓———

Quand choisir un autre outil

For very high-volume production with a closed K7 dedicated-printer flow, PiezoDN remains the reference — but at a high entry and learning cost. CF positions itself as the short path to an `.acv` curve (Pro mode) usable in Photoshop without additional hardware.

Détails complets dans le manuel

FAQ

Questions from platinum/palladium practitioners.

Going further

Platinum/palladium is not in the Vision Picturale range.

The Picturale ecosystem covers six UV-exposure processes — cyanotype, gum bichromate, carbon, bromoil, gumoil, resinotype (carbon is still in development at Vision Picturale, not yet sold). Platinum/palladium stays outside it. Calibration Flow calibrates it anyway, independently of your chemistry or paper supplier. You import your scanned target like for any alt-process, export your .acv curve (Pro mode), and apply it in Photoshop before your print.

A few references if you are starting Pt/Pd:

  • Chemistry — Bostick & Sullivan (historical US reference, complete Pt/Pd kits) and Photographers' Formulary offer ready-to-measure sensitiser + developer kits.
  • Paper — Hahnemühle Platinum Rag, Arches Platine, Bergger Cot 320. 100 % cotton, neutral pH, no optical brighteners, 300 gsm+.
  • Reading — Christopher James, The Book of Alternative Process Photography, the Pt/Pd chapter with precise ratios and bath times.
  • See a reference print — Maison Picturale prints in platinum-palladium in its Paris workshop. Useful to compare your calibration print against a workshop reference.
  • Calibration — open Calibration Flow, follow the step-by-step. Your platinum/palladium produces the target, the app generates your curve, your workflow is calibrated within two weeks.

Do you also practise a Vision Picturale process in parallel (cyanotype, gum bichromate, carbon…)? See the six ecosystem processes →

Calibrate before committing the platinum. The economic rule.

Free with registration on the Web version: target, curve and negative included, no credit card required. Pro Mode (€9.90/month) adds .acv export and extended quotas.

Try it free — no credit card